Tetragonal
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4/m 2/m 2/m (D4h)
90度で交わる3軸で2軸が等長 (a = b ≠ c, alpha = beta = gamma = 90°)
正方晶系は互いに直交する3軸を持ち、そのうち2軸が等長です。結晶はしばしば細長い柱状または両錐形態を示します。代表例にはジルコン、金紅石、錫石、ベスブ石などがあります。
The tetragonal crystal system has three mutually perpendicular axes, with two of equal length and one different (a = b ≠ c, all at 90°). This creates crystals with a square cross-section — elongated or compressed cubes. About 7% of known minerals crystallize in this system. Tetragonal symmetry sits between the high symmetry of cubic and the lower symmetry of orthorhombic, producing elegant prismatic crystals with distinctive four-fold symmetry.
Symmetry
Tetragonal crystals have one four-fold rotation axis (the c-axis) and may have additional two-fold axes and mirror planes. The square cross-section (a = b) with a different c-axis length means crystals look the same after 90° rotation around the c-axis but different if rotated around a or b. The system contains 7 crystal classes. Common crystal forms include tetragonal prisms {100} and {110}, dipyramids, and the distinctive square outline visible in cross-section. Many tetragonal minerals form stubby to elongate prismatic crystals with square or octagonal outlines.
注目の鉱物
Zircon (ZrSiO₄) is the most famous tetragonal mineral — the oldest known material on Earth, with crystals from Western Australia dated at 4.4 billion years. Rutile (TiO₂) forms slender tetragonal prisms that often penetrate quartz crystals as golden needle-like inclusions. Cassiterite (SnO₂), the primary tin ore, forms distinctive twinned tetragonal crystals. Wulfenite (PbMoO₄) is prized by collectors for its thin, square tabular crystals in vivid orange and yellow. Scapolite forms columnar tetragonal crystals and is used as a gemstone in yellow and purple varieties.
鉱物 (4)
Zircon
ZrSiO4
09 Silicates
Cassiterite
SnO2
04 Oxides and Hydroxides
Chalcopyrite
CuFeS2
02 Sulfides and Sulfosalts
Rutile
TiO2
04 Oxides and Hydroxides